Chiral Catalysis at the Water/Oil Interface
Chiral Catalysis at the Water/Oil Interface
复制标题
水/油界面的手性催化
DOI：
10.1021/acscatal.7b02118
复制
发表时间：
2018-01-01
期刊：
影响因子：
12.9
通讯作者：
Li, Can
中科院分区：
文献类型：
--
作者：
Guo, Wengang;Liu, Xianghui;Li, Can
水作为溶剂的独特物理化学性质多年来引起了合成化学家的极大兴趣，关于水相条件下的化学反应的研究取得了巨大进展。其中，催化不对称反应也得到了证实，水不仅是一种独特的溶剂，而且也参与了反应。在这个角度，我们总结和讨论在水/油界面的手性催化的最新进展。重点放在手性有机催化和金属催化中使用的概念/方法。
The unique physicochemical properties of water as a solvent have attracted great interest from synthetic chemists for many years, and tremendous research progress on chemical reactions under aqueous conditions has been reported. Among them, catalytic asymmetric reactions have also been demonstrated and water turns out to not only be a unique solvent but also participate in the reactions. In this Perspective, we summarize and discuss recent advances in chiral catalysis at the water/oil interface. Emphasis is placed on the concepts/approaches used in chiral organocatalysis and metal catalysis.