Synthesis, crystal structure and homogeneous catalytic activity towards ethylene polymerisation of the spirocyclic chromium(II) siloxane [C[graphic ommitted])-µ-Na(thf)2}2](thf = tetrahydrofuran)

Synthesis, crystal structure and homogeneous catalytic activity towards ethylene polymerisation of the spirocyclic chromium(II) siloxane [C[graphic ommitted])-µ-Na(thf)2}2](thf = tetrahydrofuran)
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螺环铬(II)硅氧烷[C[图略])-μ-Na(thf)2}2](thf = 四氢呋喃)的合成、晶体结构和乙烯聚合均相催化活性

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发表时间:
1993
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通讯作者:
A. Sullivan
A. Sullivan
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文献类型:
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作者:
M. Motevalli;M. Sanganee;P. Savage;Syed A. A. Shah;A. Sullivan

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铬(II)化合物[C[图形省略])-µ-Na(THF)2}2]1已被分离和结构表征;与三甲基铝结合,它是乙烯聚合成线性聚乙烯的预催化剂。
The chromium(II) compound [C[graphic ommitted])-µ-Na(thf)2}2]1 has been isolated and structurally characterised; in combination with trimethylaluminium, it is a precatalyst for the polymerisation of ethene to linear polyethylene.