Construction of functional polymers from acetylenic triple-bond building blocks
Construction of functional polymers from acetylenic triple-bond building blocks
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DOI：
10.1002/macp.200800228
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发表时间：
2008-07-03
影响因子：
2.5
通讯作者：
Tang, Ben Zhong
中科院分区：
文献类型：
--
作者：
Tang, Ben Zhong
讨论了由炔属三键结构单元构筑功能高分子的方法。研究人员使用炔属结构单元，因为炔属聚合可以提供难以通过常规乙烯基聚合获得的共轭聚合物。炔属单体也具有高潜力的特性，成为构建功能性大分子的一组构件，而炔属聚合可能成为开发特种材料的有用工具。许多研究人员致力于炔属单体的聚合，以探索它们在功能聚合物中的潜力。这些努力导致了研究领域的重大发展，同时已经制备了新的炔属单体并且已经发现了新的催化剂体系。
The construction of functional polymers from acetylenic triple-bond building blocks is discussed. Researchers used acetylenic building blocks, as acetylenic polymerizations can afford conjugated polymers that are difficult to access by the conventional vinyl polymerizations. Acetylenic monomers also have high potential characteristics, to become a group of building blocks for constructing functional macromolecules, while acetylenic polymerizations may become useful tools for developing specialty materials. Many researchers have made efforts at polymerizing acetylenic monomers, to explore their potentials for the creation of functional polymers. These efforts have led to significant developments in the area of research, while new acetylenic monomers have been made and new catalyst systems have been discovered.