Synthesis, conformational and host-guest properties of water-soluble pillar[5]arene
Synthesis, conformational and host-guest properties of water-soluble pillar[5]arene
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DOI：
10.1039/c0cc00348d
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发表时间：
2010-01-01
影响因子：
4.9
通讯作者：
Nakamoto, Yoshiaki
中科院分区：
文献类型：
--
作者：
Ogoshi, Tomoki;Hashizume, Masayoshi;Nakamoto, Yoshiaki
通过在分子的上、下缘引入羧酸根阴离子，合成了水溶性柱[5]芳烃。当阳离子紫精盐与水溶性柱[5]-芳烃在水介质中混合时，形成非常稳定的1：1主-客体络合物。
Water-soluble pillar[5]arene was synthesized by the introduction of carboxylate anions at both upper and lower rims. When cationic viologen salt was mixed with the water-soluble pillar[5]-arene in aqueous media, a very stable 1 : 1 host-guest complex was formed.