Arylmagnesiation of alkynes catalyzed cooperatively by iron and copper complexes.
Arylmagnesiation of alkynes catalyzed cooperatively by iron and copper complexes.
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DOI：
10.1021/ja0542136
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发表时间：
2005-11
影响因子：
15
通讯作者：
E. Shirakawa;T. Yamagami;Takahiro Kimura;S. Yamaguchi;Tamio Hayashi
中科院分区：
文献类型：
--
作者：
E. Shirakawa;T. Yamagami;Takahiro Kimura;S. Yamaguchi;Tamio Hayashi
铁和铜配合物协同催化未官能化炔烃（包括二烷基乙炔）的芳基镁化，其中铁和铜催化剂的存在对于高产率2-芳基-1-烯基溴化镁至关重要。
Iron and copper complexes cooperatively catalyzed the arylmagnesiation of unfunctionalized alkynes including dialkylacetylenes, where the presence of both iron and copper catalysts is essential for high yields of 2-aryl-1-alkenylmagnesium bromides.