Porous Organic Polymer from Aggregation-Induced Emission Macrocycle for White-Light Emission
Porous Organic Polymer from Aggregation-Induced Emission Macrocycle for White-Light Emission
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用于白光发射的聚集诱导发射大环多孔有机聚合物
DOI：
10.1021/acs.macromol.8b01632
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发表时间：
2018-10-09
期刊：
影响因子：
5.5
通讯作者：
Zhang, Chun
中科院分区：
文献类型：
--
作者：
Wang, Zhen;Yan, Sen;Zhang, Chun
采用具有高荧光量子产率（70%）的四苯乙烯基氧杂杯芳烃大环（TOM）作为单体，构建了基于荧光大环的多孔有机聚合物（pTOM）。蓝绿荧光pTOM具有高比表面积、特定孔径和发射特性，通过福斯特共振能量转移（FRET）效应吸附具有互补发射颜色的三（联吡啶）钌客体，可开发成白光发射材料。
A tetraphenylethylene-based oxacalixarene macrocycle (TOM) with high fluorescence quantum yield (70%) was used as monomer to construct a fluorescent macrocycle-based porous organic polymer (pTOM). With high surface area, specific pore size, and emissive properties, the blue-greenish fluorescent pTOM can be developed into white-light-emission materials by adsorbing guests of tris(bipyridine)ruthenium with complementary emission color by the Forster resonance energy transfer (FRET) effect.