Electrochemical performances of Ni1-xCux/SDC cermet anodes for intermediate-temperature SOFCs using syngas fuel
Electrochemical performances of Ni1-xCux/SDC cermet anodes for intermediate-temperature SOFCs using syngas fuel
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DOI：
10.1016/j.ijhydene.2016.05.070
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发表时间：
2016-08
影响因子：
7.2
通讯作者：
M. Miyake;S. Matsumoto;Makoto Iwami;S. Nishimoto;Y. Kameshima
中科院分区：
文献类型：
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作者：
M. Miyake;S. Matsumoto;Makoto Iwami;S. Nishimoto;Y. Kameshima
Ni-based alloy cermet anodes, Ni1−xCux(x= 0.0, 0.2, 0.5, and 1.0)/Ce0.8Sm0.2O1.9(SDC), were prepared for use with syngas fuel in intermediate-temperature solid oxide fuel cells byin situreduction of Ni1−xCuxO compounds. The electrochemical performances of cells with the Ni1−xCux/SDC anodes were investigated at 700 and 600 °C, using humidified (3% H2O) syngas with H2/CO = 3/2 as the fuel. Cu doping of the Ni/SDC anode effectively suppressed carbon deposition on the anode. However, the cell performance was deteriorated with increasing amounts of Cu. The Ni0.8Cu0.2/SDC anode was found to be promising for use with syngas fuel.
