Oxygen-promoted palladium(II) catalysis: facile C(sp2)-C(sp2) bond formation via cross-coupling of alkenylboronic compounds and olefins.

Oxygen-promoted palladium(II) catalysis: facile C(sp2)-C(sp2) bond formation via cross-coupling of alkenylboronic compounds and olefins.
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DOI：
10.1021/ol0483192
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发表时间：
2004-10
期刊：
Organic letters
影响因子：
5.2
通讯作者：
C. H. Yoon;K. Yoo;S. Yi;R. Mishra;K. W. Jung
C. H. Yoon;K. Yoo;S. Yi;R. Mishra;K. W. Jung
中科院分区：
化学1区
文献类型：
--
作者：
C. H. Yoon;K. Yoo;S. Yi;R. Mishra;K. W. Jung

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[反应：氧促进的Pd（II）催化剂通过链烯基硼酸化合物和各种烯烃（包括高度取代的烯烃和环己烯酮）的交叉偶联促进了共轭二烯的合成。在温和的条件下，这些通用的反应是有效的和高度的立体选择性。
[reaction: see text] Oxygen-promoted Pd(II) catalysis facilitated the synthesis of conjugated dienes by cross-coupling of alkenylboronic compounds and various olefins including highly substituted alkenes and cyclohexenone. Under mild conditions, these versatile reactions were efficient and highly stereoselective.