Selective alkane co-inclusion by methylene- and adamantane-bridged macrocycle with biphenyl units

Selective alkane co-inclusion by methylene- and adamantane-bridged macrocycle with biphenyl units
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DOI:
10.1039/d1ce00722j
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发表时间:
2021-08
期刊:
影响因子:
3.1
通讯作者:
Masahide Tominaga;Kousuke Fujimaru;T. Hyodo;K. Yamaguchi
Masahide Tominaga;Kousuke Fujimaru;T. Hyodo;K. Yamaguchi
中科院分区:
化学3区
文献类型:
--
作者:
Masahide Tominaga;Kousuke Fujimaru;T. Hyodo;K. Yamaguchi

文献摘要

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一种具有联苯单元的亚甲基和金刚烷桥连大环化合物通过结晶在己烷异构体中显示出对正己烷的选择性共包合。在使用正戊烷或正庚烷时,没有形成与烷烃的包合晶体。
A methylene- and adamantane-bridged macrocycle with biphenyl units showed selective co-inclusion of n-hexane among the hexane isomers through crystallization. In the use of n-pentane or n-heptane, inclusion crystals with alkanes were not formed.