Palladium-Catalyzed Aerobic Dehydrogenative Aromatization of Cyclohexanone Imines to Arylamines
Palladium-Catalyzed Aerobic Dehydrogenative Aromatization of Cyclohexanone Imines to Arylamines
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DOI：
10.1021/ol302568b
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发表时间：
2012-11-02
期刊：
影响因子：
5.2
通讯作者：
Yoshikai, Naohiko
中科院分区：
文献类型：
--
作者：
Hajra, Alakananda;Wei, Ye;Yoshikai, Naohiko
在有氧条件下，用钯催化剂实现了环己酮亚胺脱氢芳构化为芳胺。该反应适用于由环己酮衍生物和芳基或烷基胺预形成或原位生成的各种亚胺。
Dehydrogenative aromatization of cyclohexanone imines to arylamines has been achieved using a palladium catalyst under aerobic conditions. The reaction is applicable to a variety of imines that are either preformed or generated in situ from cyclohexanone derivatives and aryl or alkylamines.