Chemical Kinetics and Process Dynamics in Aquatic Systems
Chemical Kinetics and Process Dynamics in Aquatic Systems
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DOI：
10.1201/9781315139135
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发表时间：
1993-12
期刊：
影响因子：
--
通讯作者：
P. Brezonik
中科院分区：
文献类型：
--
作者：
P. Brezonik
概述：导言。自然沃茨是非平衡系统。这本书的范围。化学反应的速率表达式：介绍。基本反应的速率方程。更复杂反应的速率方程。从实验数据确定速率方程和速率参数。速率方程与反应机理的关系。动力学研究的实验方面。动力学的理论方面和物理条件对反应速率的影响：介绍。方程和相关的温度关系。水和反应物在水溶液中的性质。溶液中反应的相遇理论。过渡态/活化复合物理论压力对溶液中反应速率的影响。离子强度对反应速率的影响。动力学参数的数值范围：总结和展望。水系统中化学反应的动力学：从均相催化到界面反应：均相催化。导论.均相催化的类型和机理。催化反应的速率方程。水溶液中化学反应动力学：天然沃茨中解离和水解反应动力学。氯化反应动力学。无机氧化还原反应接口处的进程。气体转移动力学矿物溶解和形成。反应器，质量传输和过程模型：反应器理论。化学反应器基础质量平衡分析原理。CFSTR和PFR的比较行为。反应器模型在自然水生系统中的应用。开放系统的平衡与动力学模型。营养模型有机污染物迁移和归宿模型。湖泊硫酸盐和碱度的CFSTR模型。多组分系统动力学。多通信系统的性质。用矩阵方法分析比较模型。逆问题。天然沃茨中生化反应和微生物过程的动力学。生化动力学：酶催化反应。涉及单一底物的反应。多底物反应。酶抑制。酶催化的理论方面。微生物过程动力学。营养限制性微生物生长动力学。微生物的连续培养。温度对微生物过程的影响。水生系统中异养生长的动力学模型。自养生长和养分吸收的动力学模型。扩散限制运输和增长。微生物死亡和消毒动力学。反应速率和化合物反应活性的预测方法。线性自由能关系导论.布朗斯台德的关系有机取代基效应的Sigma关系。氧化还原反应的LFER。LFERs在天然沃茨反应中的应用。环境生物学和化学中的性质-活性和结构-活性关系。PAR和SAR的性质和重要性。化合物可用性和可运输性的物理化学测量。线性溶剂化能关系。一个简单的生物系统性质-活性模型。水生生物的性质-活性关系。定量结构-活性关系。使用统计技术开发和分析PAR和SAR。摘要自然沃茨中的光化学反应：导论。光化学反应动力学。天然沃茨的无机光化学。天然DOM的性质和光化学。天然沃茨中有机污染物的光化学。悬浮氧化物颗粒的光化学。参考资料。指数.
Overview: Introduction. Natural Waters as Nonequalibrium Systems. Scope of This Book. Rate Expressions for Chemical Reactions: Introduction. Rate Equations for Elementary Reactions. Rate Equations for More Complicated Reactions. Determination of Rate Equations and Rate Parameters from Experimental Data. Relationships between Rate Equations and Reaction Mechanisms. Experimental Aspects of Kinetic Studies. Theoretical Aspects of Kinetics and Effects of Physical Conditions on Reaction Rates: Introduction. The Arrhenquation and Related Temperature Relationships. Properties of Water and Reactants in Aqueous Solution. Encounter Theory for Reactions in Solution. Transition State/Activated Complex theory. Effects of Pressure on Rates of Reactions in Solution. Effects of Ionic Strength on Reaction Rates. Ranges of Values for Kinetic Parameters: Summary and perspective . Kinetics of Chemical Reactions in Aquatic Systems: From Homogeneous Catalysis to Reactions at Interfaces: Homogeneous Catalysis. Introduction. Types and Mechanisms of Homogeneous Catalysis. Rate Equations for Catalyzed Reactions. Kinetics of Chemical Reactions in Aqueous Solution: Kinetics of Dissociation and Hydrolysis Reactions in Natural Waters. Kinetics of Chlorination Reactions. Inorganic Redox Reactions. Processes at Interfaces. Gas Transfer Kinetics. Mineral Dissolution and Formation. Reactors, Mass Transport, and Process Models: Reactor Theory. Fundamentals of Chemical Reactors. Principles of Mass Balance Analysis. Comparative Behavior of CFSTRs and PFRs. Applications of Reactor Models to Natural Aquatic Systems. Equilibrium versus Kinetic Models for Open Systems. Nutrient Models. Models of Organic Contaminant Transport and Fate. CFSTR Models for Sulfate and Alkalinity on Lakes. Kinetics of Multi-Compartment Systems. Nature of Multi-Compartment Systems. Analysis of Compartment Models by Matrix Methods. The Inverse Problem. Kinetics of Biochemical Reactions and Microbial Processes in Natural Waters. Biochemical Kinetics: Enzyme Catalyzed Reactions. Reactions Involving a Single Substrate. Multisubstrate Reactions. Enzyme Inhibition. Theoretical Aspects of Enzyme Catalysis. Kinetics of Microbial Processes. Kinetics of Nutrient-Limited Microbial Growth. Continuous Culture of Microorganisms. Effects of Temperature on Microbial Processes. Kinetic Models of Heterotrophic Growth in Aquatic Systems. Kinetic Models for Autotrophic Growth and Nutrient Uptake. Diffusion-Limited Transport and Growth. Microbial Dieoff and Disinfection Kinetics. Prediction Methods for Reaction Rates and Compound Reactivity. Linear Free energy Relationships. Introduction. The Bronsted Relationship. Sigma Relationships for Organic Substituent Effects. LFERs for Redox Reactions. Applications of LFERs to Reactions in Natural Waters. Property-Activity and Structure-Activity Relationships in Environmental Biology and Chemistry. Nature and Importance of PARs and SARs. Physical-Chemical Measures of Compound Availability and Transportability. Linear Solvation Energy Relationships. A Simple Property-Activity Model for Biological Systems. Property-Activity Relationships for Aquatic Organisms. Quantitative Structure-Activity Relationships. Use of Statistical Techniques to Develop and Analyze PARs and SARs. Summary. Photochemical Reactions in Natural Waters: Introduction. Kinetics of Photochemical Reactions. Inorganic Photochemistry of Natural Waters. Nature and Photochemistry of Natural DOM. Photochemistry of Organic Contaminants in Natural Waters. Photochemistry on Suspended Oxide Particles. References. Index.