Selective alkane hydroxylation and alkene epoxidation using H2O2 and Fe(II) catalysts electrostatically attached to a fluorinated surface
Selective alkane hydroxylation and alkene epoxidation using H2O2 and Fe(II) catalysts electrostatically attached to a fluorinated surface
复制标题
使用静电附着在氟化表面上的 H2O2 和 Fe(II) 催化剂进行选择性烷烃羟基化和烯烃环氧化
DOI：
10.1039/d2cc06998a
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发表时间：
2023
影响因子：
4.9
通讯作者：
Kojima Takahiko
中科院分区：
文献类型：
--
作者：
Fujisaki Hiroto;Okamura Masaya;Hikichi Shiro;Kojima Takahiko
制备了含n杂环碳元的五齿配体Fe（II）配合物，并将其静电吸附在介孔硅酸铝的全氟表面。以H2O2为氧化剂在CH3CN中催化氧化环己烷和环己烯，在烷烃羟基化和环己烯环氧化反应中表现出较高的性能和选择性。
Fe(II) complexes with pentadentate ligands, including N-heterocyclic carbene moieties, were prepared and electrostatically attached onto the perfluorinated surface of a mesoporous aluminosilicate. The heterogeneous catalysts were applied to the catalytic oxidation of cyclohexane and cyclohexene using H2O2 as an oxidant in CH3CN, demonstrating high performance and selectivity in alkane hydroxylation and cyclohexene epoxidation.