Iridium Complex-Catalyzed Transfer Hydrogenation of N-Heteroarenes and Tentative Asymmetric Synthesis.
Iridium Complex-Catalyzed Transfer Hydrogenation of N-Heteroarenes and Tentative Asymmetric Synthesis.
复制标题
DOI：
10.1021/acsomega.1c00868
复制
发表时间：
2021-04-20
期刊：
影响因子：
4.1
通讯作者：
Luo R
中科院分区：
文献类型：
--
作者：
Ouyang L;Xia Y;Liao J;Miao R;Yang X;Luo R
An iridium-catalyzed transfer hydrogenation of N-heteroarenes to access a series of substituted 1,2,3,4-tetrahydroquinoline derivatives in excellent yields is disclosed. This transformation is distinguished with water-soluble and air-stable iridium complexes as the catalyst, formic acid as the hydrogen source, mild reaction conditions, and broad functional group compatibility. Most importantly, a tentative chiral N,N-chelated Cp*Ir(III) complex-catalyzed enantioselective transfer hydrogenation is also presented, affording chiral products in excellent yields and good enantioselectivities.
登录
查看更多内容
影响因子：
5.2
作者：
Iosub AV;Stahl SS
通讯作者：
Stahl SS
影响因子：
2.3
作者：
Bäckvall, JE
通讯作者：
Bäckvall, JE
影响因子：
2.7
作者：
Baumann M;Baxendale IR
通讯作者：
Baxendale IR
影响因子：
5.4
作者：
John, Joshni;Wilson-Konderka, Cody;Metallinos, Costa
通讯作者：
Metallinos, Costa
影响因子：
8.4
作者：
Carter N;Li X;Reavey L;Meijer AJHM;Coldham I
通讯作者：
Coldham I