Photochemical hydrogen production based on the HCOOH/CO2 cycle promoted by a pentanuclear cobalt complex
Photochemical hydrogen production based on the HCOOH/CO2 cycle promoted by a pentanuclear cobalt complex
复制标题
基于五核钴配合物促进的 HCOOH/CO2 循环的光化学制氢
DOI：
10.1039/d1cc06445b
复制
发表时间：
2022
影响因子：
4.9
通讯作者：
Masaoka Shigeyuki
中科院分区：
文献类型：
--
作者：
Akai Takuya;Kondo Mio;Saga Yutaka;Masaoka Shigeyuki
第一个催化循环的基础上的光化学双电子还原二氧化碳（CO2）和甲酸脱氢在环境温度下使用的五核钴配合物（Co5）的氢生产证明。进行了一系列的机制研究，以阐明负责的机制，促进光催化循环的钴。
The first catalytic cycle for hydrogen production based on the photochemical two-electron reduction of carbon dioxide (CO2) and the dehydrogenation of formic acid at ambient temperature was demonstrated using a pentanuclear cobalt complex (Co5). A series of mechanistic studies were performed to elucidate the mechanism responsible for the promotion of the photocatalytic cycle by Co5.