A Two-Step Catalytic Cycle for the Acceptorless Dehydrogenation of Ethane by Group 10 Metal Complexes: Role of the Metal in Reactivity and Selectivity
A Two-Step Catalytic Cycle for the Acceptorless Dehydrogenation of Ethane by Group 10 Metal Complexes: Role of the Metal in Reactivity and Selectivity
复制标题
DOI：
10.1021/acs.organomet.0c00598
复制
发表时间：
2020-11
期刊：
影响因子：
2.8
通讯作者：
K. Parker;Geethika K. Weragoda;A. Canty;Anastasios Polyzos;V. Ryzhov;R. O'hair
中科院分区：
文献类型：
--
作者：
K. Parker;Geethika K. Weragoda;A. Canty;Anastasios Polyzos;V. Ryzhov;R. O'hair
通过涉及三元阳离子金属氢化物 [(phen)M(H)]+, 1 和金属乙烷 [(phen)M(CH2CH3)] 的两步催化循环，在气相中实现了乙烷无受体脱氢。
Acceptorless dehydrogenation of ethane was achieved in the gas phase via a two-step catalytic cycle involving ternary cationic metal hydrides, [(phen)M(H)]+, 1, and metal ethides, [(phen)M(CH2CH3)]...