Ni0-catalyzed regio- and stereoselective coupling reaction of Me3B, isoprene, and aldehydes
Ni0-catalyzed regio- and stereoselective coupling reaction of Me3B, isoprene, and aldehydes
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DOI：
10.1016/s0040-4039(00)01079-0
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发表时间：
2000-08-26
影响因子：
1.8
通讯作者：
Tamaru, Y
中科院分区：
文献类型：
--
作者：
Kimura, M;Shibata, K;Tamaru, Y
在Ni(acac)(2)（0.1当量）存在下，三甲基硼烷、异戊二烯、芳香醛和脂肪醛三组分结合生成1-取代3-甲基-3-己烯醇(3)，产率高，区域选择性和立体选择性高（E:Z>13:1）。(C) 2000 Elsevier Science Ltd.版权所有。
In the presence of Ni(acac)(2) (0.1 equiv.), the three components of trimethylborane, isoprene, and aromatic and aliphatic aldehydes combine to produce 1-substituted 3-methyl-3-hexenols (3) in good yield and with high regio- and stereoselectivity (E:Z>13:1). (C) 2000 Elsevier Science Ltd. All rights reserved.