Solid Surface Enhancement Effects on Chemiluminescence. III. Diaryloxalate as Chemiluminescence Reagent and Inorganic Materials as Media Solids
Solid Surface Enhancement Effects on Chemiluminescence. III. Diaryloxalate as Chemiluminescence Reagent and Inorganic Materials as Media Solids
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固体表面对化学发光的增强作用。
DOI：
10.1246/bcsj.74.1507
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发表时间：
2001
期刊：
影响因子：
--
通讯作者：
T. Hoshi
中科院分区：
文献类型：
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作者：
T. Yoshinaga;Y. Tanaka;T. Ichimura;H. Hiratsuka;M. Hasegawa;Michio. Kobayashi;T. Hoshi
以多种无机材料为固体介质，研究了固体表面增强效应对化学发光的影响。结果如下：第一组(G-1)与参考化学发光(空白CL；使用的介质固体为载玻片玻璃)-Al_2O_3系列(包括氢氧化物和玻璃纤维滤光片)相比具有较高的初始强度和较短的寿命(G-1)属于该组(G-1)，第二组(G-2)与空白CL-高纯CaCO3相比具有较低的初始强度和较长的寿命(G-2)。第三组(G-3)与空白CL-SiO_2粉末和石英纤维滤光片相比具有更高的初始强度和更长的寿命，属于该组(G-3)；以及与空白CL相比具有更低初始强度和更短寿命的第四组(G-4)-除(G-1)-(G-3)组外的所有剩余固体介质属于该组(G-4)。此外，从化学发光能量的角度来看，还存在其他的…
Solid surface enhancement effects on chemiluminescence were studied using many inorganic materials as solid media. The results has been classified as follows: the first group (G-1) which has higher initial intensities and shorter lifetimes compared with the reference chemiluminescence (blank CL; medium solid used is a slide glass)—Al2O3 series including hydroxides and glass fiber filter fall under this group (G-1); the second group (G-2) which has lower initial intensities and longer lifetimes compared with the blank CL—high purity CaCO3 fall under this group (G-2); the third group (G-3) which has higher initial intensities and longer lifetimes compared with the blank CL—SiO2 powder and a silica fiber filter fall under this group (G-3); and the fourth group (G-4) which has lower initial intensities and shorter lifetimes compared with the blank CL—all remaining solid media other than group (G-1)–(G-3) fall under this group (G-4). Furthermore, from a chemiluminescent energy point of view, there exists anoth...