Utilisation of GaN and InGaN/GaN with nanoporous structures for water splitting

Utilisation of GaN and InGaN/GaN with nanoporous structures for water splitting
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DOI:
10.1063/1.4903246
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发表时间:
2014-12-01
影响因子:
4
通讯作者:
Wang, T.
Wang, T.
中科院分区:
物理与天体物理2区
文献类型:
--
作者:
Benton, J.;Bai, J.;Wang, T.

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我们报告了一种经济有效的方法来制造基于 GaN 的纳米多孔结构,用于可再生氢生产的应用。 KOH 溶液中的光电化学蚀刻已被用来制造 GaN 和 InGaN/GaN 纳米多孔结构,孔径范围为 25 至 60 nm,通过控制蚀刻剂浓度和施加电压获得。与生长的平面器件相比,纳米多孔结构的光电流显着增加,高达四倍。 GaN 能带边缘附近的入射光子转换效率高达 46%。 (C) 2014 AIP 出版有限责任公司。
We report a cost-effective approach to the fabrication of GaN based nanoporous structure for applications in renewable hydrogen production. Photoelectrochemical etching in a KOH solution has been employed to fabricate both GaN and InGaN/GaN nanoporous structures with pore sizes ranging from 25 to 60 nm, obtained by controlling both etchant concentration and applied voltage. Compared to as-grown planar devices the nanoporous structures have exhibited a significant increase of photocurrent with a factor of up to four times. An incident photon conversion efficiency of up to 46% around the band edge of GaN has been achieved. (C) 2014 AIP Publishing LLC.