Porphyrinoid f-Element Complexes
Porphyrinoid f-Element Complexes
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DOI：
10.1021/acs.inorgchem.9b00884
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发表时间：
2020-01-06
影响因子：
4.6
通讯作者：
Sessler, Jonathan L.
中科院分区：
文献类型：
--
作者：
Brewster, James T., II;Zafar, Hadiqa;Sessler, Jonathan L.
卟啉和相关的含吡咯的大环，统称为卟啉类化合物，是一种多功能的配体，允许进入多种配位模式。对卟啉核心和侧基的合理修饰扩大了卟啉类化合物的配位化学，包括能够稳定f-嵌段元素络合物的系统，可能具有实用价值。本文综述了我们课题组为制备可作为研究和应用f元素金属配位化学工具的扩展的卟啉和卟啉原配体所做的努力：包括选题背景、选择的合成方法以及这些物种在化学和医学科学中的应用。
Porphyrin and related pyrrole-containing macrocycles, collectively porphyrinoids, are versatile ligands that allow access to a multitude of coordination modes. Judicious modification of the porphyrin core as well as the pendant substituents has extended the coordination chemistry of porphyrinoids to include systems that are able to stabilize f-block element complexes with possible utility. This review focuses on our group's efforts to prepare expanded porphyrin and porphyrinogen ligands that can serve as tools to study and apply f-element metal coordination chemistry: it covers the background of the topic, selected syntheses, and application of these species in the chemical and medical sciences.