Step-by-step synthesis of one Fe6 wheel and two Fe10 clusters derived from a multidentate triethanolamine ligand
Step-by-step synthesis of one Fe6 wheel and two Fe10 clusters derived from a multidentate triethanolamine ligand
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DOI：
10.1039/c3ce42381f
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发表时间：
2014-05
期刊：
影响因子：
3.1
通讯作者：
Suijun Liu;Songde Han;Ji-Min Jia;L. Xue;Yu Cui;Shu-Ming Zhang;Ze Chang
中科院分区：
文献类型：
--
作者：
Suijun Liu;Songde Han;Ji-Min Jia;L. Xue;Yu Cui;Shu-Ming Zhang;Ze Chang
采用分步的方法得到了一个Fe 6轮和两个Fe 10团簇。以Fe_3O为前驱体，三乙醇胺为催化剂，合成了轮状和簇合物。磁性研究表明，Fe_6砂轮具有较强的反铁磁行为。
One Fe6 wheel and two Fe10 clusters were obtained with a step-by-step strategy. The wheel and cluster complexes were synthesized by reacting Fe3O precursors with triethanolamine. A magnetic investigation indicates that the Fe6 wheel shows strong antiferromagnetic behavior.