Rational serendipity: "undirected" synthesis of a large {MnCu} complex from pre-formed MnII building blocks.
Rational serendipity: "undirected" synthesis of a large {MnCu} complex from pre-formed MnII building blocks.
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合理的偶然性:从预先形成的 MnII 结构单元“非定向”合成大型 {MnCu} 配合物。
DOI:
10.1039/c6dt03914f
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发表时间:
2016
期刊:
影响因子:
--
通讯作者:
Frost JM
中科院分区:
文献类型:
--
作者:
Frost JM
Use of an aminopolyalcohol-based MnII complex in solvothermal CuII chemistry leads to a rare example of a high nuclearity heterometallic {MnIII10CuII5} system, in which four CuII(H1Edte) units trap an inner {MnIII10CuII} oxide core.