Rational serendipity: "undirected" synthesis of a large {MnCu} complex from pre-formed MnII building blocks.

Rational serendipity: "undirected" synthesis of a large {MnCu} complex from pre-formed MnII building blocks.
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合理的偶然性:从预先形成的 MnII 结构单元“非定向”合成大型 {MnCu} 配合物。

DOI:
10.1039/c6dt03914f
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发表时间:
2016
期刊:
2003)
影响因子:
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通讯作者:
Frost JM
Frost JM
中科院分区:
--
文献类型:
--
作者:
Frost JM

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在溶剂热CuII化学中使用基于氨基多元醇的MnII配合物导致了一个罕见的高核性杂金属{MnIII 10 CuII 5}系统的例子,其中四个CuII(H1 Edte)单元捕获了内部{MnIII 10 CuII}氧化物核心。
Use of an aminopolyalcohol-based MnII complex in solvothermal CuII chemistry leads to a rare example of a high nuclearity heterometallic {MnIII10CuII5} system, in which four CuII(H1Edte) units trap an inner {MnIII10CuII} oxide core.