Die Kristallstruktur des Kalium-tri-isocyanatocadmats KCd(NCO)3 / The Crystal Structure of KCd(NCO)3
Die Kristallstruktur des Kalium-tri-isocyanatocadmats KCd(NCO)3 / The Crystal Structure of KCd(NCO)3
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Die Kristallstruktur des Kalium-tri-isocyanatocadmats KCd(NCO)3 / KCd(NCO)3 的晶体结构
DOI：
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发表时间：
1975
期刊：
影响因子：
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通讯作者：
P. Hilfrich
中科院分区：
文献类型：
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作者：
G. Thiele;P. Hilfrich
用三维X射线衍射法测定了KCd（NCO）_3的晶体结构。晶体为正交晶系，空间群Pnma，晶胞尺寸a = 999.3 pm，B = 367.1 pm和c = 1835.4 pm。镉原子被六个N原子八面体包围。与KCdCl 3结构一样，形成了沿着c轴的N-桥连双链，这些双链通过钾原子连接在一起。
The crystal structure of KCd(NCO)3 has been determinated by threedimensional X-ray diffraction. The crystals are orthorhombic, space group Pnma with the cell dimensions a = 999.3 pm, b = 367.1 pm and c = 1835.4 pm. The cadmium atoms are surrounded octahedrally by six N-atoms. As in the KCdCl3-structure N-bridged double chains along the c-axis are formed which are linked together by the potassium atoms.