Pd-catalyzed thiocarbamoylation of terminal alkynes with sulfenamide and carbon monoxide

Pd-catalyzed thiocarbamoylation of terminal alkynes with sulfenamide and carbon monoxide
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DOI:
10.1016/j.tetlet.2005.12.016
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发表时间:
2006-02-13
影响因子:
1.8
通讯作者:
Kambe, N
Kambe, N
中科院分区:
化学4区
文献类型:
--
作者:
Kuniyasu, H;Kato, T;Kambe, N

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以2,4,5-tri-Cl-C_6H_2SNET_2为反应底物,PdCl_2(PPh_3)(2)/PPh_3/n-Bu_4 NCl为催化剂,成功地进行了端炔的区域和立体选择性硫代氨基甲酰基化反应。(c)2005爱思唯尔有限公司保留所有权利。
Regio- and stereoselective thiocarbamoylation of terminal alkynes Successfully took place Using 2,4,5-tri-Cl-C6H2SNEt2 as a reaction substrate and PdCl2(PPh3)(2)/PPh3/n-Bu4NCl as a catalyst system. (c) 2005 Elsevier Ltd. All rights reserved.