Resonant Femtosecond Stimulated Raman Spectra: Theory and Simulations.
Resonant Femtosecond Stimulated Raman Spectra: Theory and Simulations.
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共振飞秒受激拉曼光谱:理论与模拟
DOI:
10.1021/acs.jpca.5b12316
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发表时间:
2016
期刊:
影响因子:
--
通讯作者:
W. Domcke
中科院分区:
文献类型:
--
作者:
B. J. Rao;M. F. Gelin;W. Domcke
We present a description of resonant femtosecond stimulated Raman spectra, which is based on the solution of the nonperturbative equation of motion of the chromophore in the laser fields. The theory is applicable for arbitrary shapes and durations of the Raman pulses, accounts for excited-state absorption, and describes nonstationary preparation of the system by an actinic pulse. The method is illustrated by the calculation of femtosecond stimulated Raman spectra of a model system with a conical intersection.
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