Resonant Femtosecond Stimulated Raman Spectra: Theory and Simulations.

Resonant Femtosecond Stimulated Raman Spectra: Theory and Simulations.
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共振飞秒受激拉曼光谱:理论与模拟

DOI:
10.1021/acs.jpca.5b12316
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发表时间:
2016
期刊:
The journal of physical chemistry. A
影响因子:
--
通讯作者:
W. Domcke
W. Domcke
中科院分区:
--
文献类型:
--
作者:
B. J. Rao;M. F. Gelin;W. Domcke

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本文描述了共振飞秒受激拉曼光谱,它是基于色团在激光场中的非微扰运动方程的解。该理论适用于任意形状和持续时间的拉曼脉冲,占激发态吸收,并描述了非稳态制备系统的光化脉冲。通过对一个具有圆锥形交叉口的模型系统的飞秒受激拉曼光谱的计算,说明了该方法。
We present a description of resonant femtosecond stimulated Raman spectra, which is based on the solution of the nonperturbative equation of motion of the chromophore in the laser fields. The theory is applicable for arbitrary shapes and durations of the Raman pulses, accounts for excited-state absorption, and describes nonstationary preparation of the system by an actinic pulse. The method is illustrated by the calculation of femtosecond stimulated Raman spectra of a model system with a conical intersection.
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