Possible role for Cu(II) compounds in the oxidation of malonyl dichloride and HCl at Cu(110) surfaces
Possible role for Cu(II) compounds in the oxidation of malonyl dichloride and HCl at Cu(110) surfaces
复制标题
Cu(II) 化合物在 Cu(110) 表面丙二酰二氯和 HCl 氧化中的可能作用
DOI:
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发表时间:
2009
期刊:
影响因子:
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通讯作者:
D. Richards
中科院分区:
文献类型:
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作者:
P. R. Davies;D. Edwards;D. Richards
The pathway for the chlorination of Cu(110) surfaces by malonyl dichloride and HCl is changed in the presence of oxygen with STM results suggesting the formation of a surface CuCl2 state at room temperature that may have implications for mechanistic models of the Deacon process and of dioxin formation at aerosol particle surfaces.