Possible role for Cu(II) compounds in the oxidation of malonyl dichloride and HCl at Cu(110) surfaces

Possible role for Cu(II) compounds in the oxidation of malonyl dichloride and HCl at Cu(110) surfaces
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Cu(II) 化合物在 Cu(110) 表面丙二酰二氯和 HCl 氧化中的可能作用

DOI:
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发表时间:
2009
期刊:
影响因子:
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通讯作者:
D. Richards
D. Richards
中科院分区:
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文献类型:
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作者:
P. R. Davies;D. Edwards;D. Richards

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在有氧存在的情况下,丙二酰二氯和 HCl 氯化 Cu(110) 表面的途径发生了改变,STM 结果表明在室温下形成了表面 CuCl2 态,这可能对迪肯过程和气溶胶颗粒表面二恶英形成的机械模型有影响。
The pathway for the chlorination of Cu(110) surfaces by malonyl dichloride and HCl is changed in the presence of oxygen with STM results suggesting the formation of a surface CuCl2 state at room temperature that may have implications for mechanistic models of the Deacon process and of dioxin formation at aerosol particle surfaces.