Direct one-pot conversion of acylated carbohydrates into their alkylated derivatives under heterogeneous reaction conditions using solid NaOH and a phase transfer catalyst
Direct one-pot conversion of acylated carbohydrates into their alkylated derivatives under heterogeneous reaction conditions using solid NaOH and a phase transfer catalyst
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DOI：
10.1016/j.carres.2005.03.007
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发表时间：
2005-05-23
影响因子：
3.1
通讯作者：
Misra, AK
中科院分区：
文献类型：
--
作者：
Madhusudan, SK;Agnihotri, G;Misra, AK
在固体氢氧化钠和相转移催化剂的存在下，利用烷基卤化物直接将烷基保护碳水化合物转化为烷基化碳水化合物。这些经济方便，温和，两相反应条件允许制备各种单糖中间体用于合成复杂的低聚糖。(c) 2005年Elsevier Ltd出版
A convenient one-pot protocol for the direct conversion of acyl-protected carbohydrates into their alkylated Counterparts has been developed by using alkyl halides in the presence of solid sodium hydroxide and a phase transfer catalyst. These economically convenient, mild, two-phase reaction conditions allow the preparation of a variety of monosaccharide intermediates for use in the synthesis of complex oligosaccharides. (c) 2005 Published by Elsevier Ltd.