Asymmetric Hydroformylation
Asymmetric Hydroformylation
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DOI：
10.1007/3418_016
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发表时间：
2006-01-01
期刊：
影响因子：
--
通讯作者：
Castillon, Sergio
中科院分区：
文献类型：
--
作者：
Claver, Carmen;Dieguez, Montserrat;Castillon, Sergio
本章介绍了烯烃不对称加氢甲酰化的最新成果。它重点关注含有二亚磷酸酯和膦-亚磷酸酯配体的铑体系，因为它们在该主题中具有重要意义。特别关注乙烯基芳烃加氢甲酰化中间体的机理和表征，因为这些是该领域最重要的突破。由于其工业相关性，本章还介绍了该催化反应在乙酸乙烯酯、二氢呋喃和不饱和腈中的应用。
This chapter presents the latest achievements reported in the asymmetric hydroformylation of olefins. It focuses on rhodium systems containing diphosphites and phosphine-phosphite ligands, because of their significance in the subject. Particular attention is paid to the mechanistic aspects and the characterization of intermediates in the hydroformylation of vinyl arenes because these are the most important breakthroughs in the area. The chapter also presents the application of this catalytic reaction to vinyl acetate, dihydrofurans and unsaturated nitriles because of its industrial relevance.