PNICTIDE OXIDES - A UNIQUE CLASS OF COMPOUNDS
PNICTIDE OXIDES - A UNIQUE CLASS OF COMPOUNDS
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DOI：
10.1080/02603599508033858
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发表时间：
1995-01-01
影响因子：
5.4
通讯作者：
KAUZLARICH, SM
中科院分区：
文献类型：
--
作者：
BROCK, SL;KAUZLARICH, SM
层状磷灰石氧化物是一类不同寻常的化合物，很少受到关注。这些材料的特征是存在相互不结合的镍氧原子，它们被认为是阴离子。这类化合物是由碱金属或稀土金属的三元锡石氧化物和碱金属或碱土金属的四元锡石氧化物以及过渡金属组成的。这篇评论讨论了这一小群化合物的结构和成键。此外，还介绍了许多过渡金属杂多酸化合物的磁学和电学性质。
Layered pnictide oxides are an unusual class of compounds which have received little attention. The characteristic feature of these materials is the presence of pnictogen and oxygen atoms which are not bonded to each other and are considered to be anions. This class of compounds is made up of ternary pnictide oxides of alkaline or rare earth metals, and quaternary pnictide oxides of alkali or alkaline earth metal along with transition metals. This Comment discusses structure and bonding in this small group of compounds. Additionally, magnetic and electronic properties of many of the transition metal pnictide oxide compounds are presented.