Facile Preparation of Anion Trapping Polymer Electrolytes by Reaction between 9-Borabicyclo[3. 3. 1]nonane (9-BBN) and Poly(propylene oxide)

Facile Preparation of Anion Trapping Polymer Electrolytes by Reaction between 9-Borabicyclo[3. 3. 1]nonane (9-BBN) and Poly(propylene oxide)
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通过 9-Borabicyclo[3] 之间的反应轻松制备阴离子捕获聚合物电解质。

DOI:
10.1246/cl.2004.396
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发表时间:
2004
期刊:
影响因子:
1.6
通讯作者:
H. Ohno
H. Ohno
中科院分区:
化学4区
文献类型:
--
作者:
T. Mizumo;K. Sakamoto;N. Matsumi;H. Ohno

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通过聚环氧丙烷低聚物与9-硼双环[3.3.1]壬烷的反应,制备了一种新型的聚合物电解质,其锂离子迁移数大于0.5,这是由于硼原子的阴离子捕获效应。
Novel polymer electrolyte showing relatively high lithium ion transference number of over 0.5 due to anion trapping effect of boron atoms was readily prepared by the reaction between poly(propylene oxide) oligomers and 9-borabicyco[3.3.1]nonane.
S.Tabata:“路易斯酸性硼酸酯单体的合成及其添加到电解质溶液和聚合物凝胶电解质中对其离子传输性能的影响”Electrochim.Acta。
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