Synthesis of chiral tertiary trifluoromethyl alcohols by asymmetric nitroaldol reaction with a Cu(II)-bisoxazolidine catalyst
Synthesis of chiral tertiary trifluoromethyl alcohols by asymmetric nitroaldol reaction with a Cu(II)-bisoxazolidine catalyst
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DOI：
10.1039/c0cc02378g
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发表时间：
2010-01-01
影响因子：
4.9
通讯作者：
Wolf, Christian
中科院分区：
文献类型：
--
作者：
Xu, Hanhui;Wolf, Christian
报道了一种高对映选择性和非对映选择性的铜(II)-二恶唑烷催化的三氟甲基酮与硝基-羟醛缩合反应。
A highly enantioselective and diastereoselective copper(II)-bisoxazolidine catalyzed nitroaldol reaction with aliphatic and aromatic trifluoromethyl ketones is described.