Effect of alkali cations on two-dimensional networks of two new quaternary thioarsenates (III) prepared by a facile surfactant-thermal method
Effect of alkali cations on two-dimensional networks of two new quaternary thioarsenates (III) prepared by a facile surfactant-thermal method
复制标题
碱金属阳离子对通过简单的表面活性剂热法制备的两种新型季硫砷酸盐（III）的二维网络的影响
DOI：
10.1016/j.jssc.2016.05.035
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发表时间：
2016-09
影响因子：
3.3
通讯作者：
Liu Yi
中科院分区：
文献类型：
--
作者：
Yan Dongming;Hou Peipei;Liu Chang;Chai Wenxiang;Zheng Xuerong;Zhang Luodong;Zhi Mingjia;Zhou Chunmei;Liu Yi
Two new quaternary thioarsenates(III) NaAg2AsS3·H2O (1) and KAg2AsS3(2) with high yields have been successfully prepared through a facile surfactant-thermal method. It is interesting that 2 can only be obtained with the aid of ethanediamine (en), which indicates that weak basicity of solvent is beneficial to the growth of 2 compared with 1. Both 1 and 2 feature the similar two-dimensional (2D) layer structures. However, the distortion of the primary honeycomb-like nets in 2 is more severe than that of 1, which demonstrates that Na+and K+cations have different structure directing effects on these two thioarsenates(III). Both experimental and theoretical studies confirm 1 and 2 are semiconductors with band gaps in the visible region. Our success in preparing these two quaternary thioarsenates(III) proves that surfactant-thermal technique is a powerful yet facile synthetic method to explore new complex chalcogenides.
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影响因子：
3.1
作者：
Kai-Yao Wang;M. Feng;D. Kong;Shijing Liang;Ling Wu;Xiaoying Huang
通讯作者：
Kai-Yao Wang;M. Feng;D. Kong;Shijing Liang;Ling Wu;Xiaoying Huang
影响因子：
6.2
作者：
L. Karanović;D. Poleti;T. Balić-Žunić;E. Makovicky;I. Grzetic
通讯作者：
L. Karanović;D. Poleti;T. Balić-Žunić;E. Makovicky;I. Grzetic
影响因子：
7
作者：
Weiwei Xiong;Guodong Zhang;Qichun Zhang
通讯作者：
Weiwei Xiong;Guodong Zhang;Qichun Zhang
影响因子：
8.6
作者：
Quansheng Guo;M. Chan;Bryan A. Kuropatwa;H. Kleinke
通讯作者：
Quansheng Guo;M. Chan;Bryan A. Kuropatwa;H. Kleinke
DOI：
10.1103/physrevb.54.2428
发表时间：
1996-07
期刊：
Physical review. B, Condensed matter
影响因子：
--
作者：
Perrin;Wimmer
通讯作者：
Perrin;Wimmer