Monoradical-containing four-coordinate Co(iii) complexes: homolytic S-S and Se-Se bond cleavage and catalytic isocyanate to urea conversion under sunlight.
Monoradical-containing four-coordinate Co(iii) complexes: homolytic S-S and Se-Se bond cleavage and catalytic isocyanate to urea conversion under sunlight.
复制标题
含单价四配位 Co(iii) 配合物：均裂 S-S 和 Se-Se 键断裂以及阳光下催化异氰酸酯转化为尿素。
作者：
G. C. Paul;Samir Ghorai;C. Mukherjee
四配位、含单自由基的 Co(iii) 配合物参与非无害配体驱动的 S-S 和 Se-Se 键均裂，并在阳光刺激下在干燥 CH2Cl2 中催化 RNCO（R = 苯基和萘基）转化为相应的脲衍生物 (TON 480)。
Four-coordinate, monoradical-containing Co(iii) complexes participated in the non-innocent ligand driven homolytic cleavage of S-S and Se-Se bonds and catalyzed the conversion of RNCO (R = phenyl and naphthyl) to the corresponding urea derivatives (TON 480) in dry CH2Cl2 under sunlight stimulus.
与氧化还原活性钴络合物的（电）催化 C-C 键形成反应
影响因子：
4.9
作者：
M. van der Meer;Y. Rechkemmer;I. Peremykin;S. Hohloch;M.G. Sommer;J. van Slageren;B. Sarkar
通讯作者：
B. Sarkar