2,3-Dihydrofuran: A Special Vinyl Ether for Cationic Photopolymerization

2,3-Dihydrofuran: A Special Vinyl Ether for Cationic Photopolymerization
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2,3-二氢呋喃:一种用于阳离子光聚合的特殊乙烯基醚

DOI:
10.1021/bk-2003-0847.ch018
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发表时间:
2003
影响因子:
2.7
通讯作者:
H. Braun
H. Braun
中科院分区:
农林科学3区
文献类型:
--
作者:
O. Nuyken;H. Braun

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以2,5-二氢呋喃和各种芳基溴化物为原料,通过Heck反应合成了含2,3-二氢呋喃的单官能团和双官能团单体。合成的单体用典型的阳离子光引发剂进行聚合。根据所用单体的类型,形成了可溶和不溶的聚合物,并研究了其热性能。
Mono- and bifunctionl monomers with 2,3-dihydrofuran moieties were synthesized by the Heck reaction of 2,5-dihydrofuran and various arylbromides. The synthesized monomers were polymerized by typical cationic photoinitiators. Depending upon the type of monomers used, soluble and insoluble polymers were formed and the thermal properties were studied.