Trace constituents of Lippia integrifolia

Trace constituents of Lippia integrifolia
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DOI:
10.1021/np50125a010
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发表时间:
1995-11
影响因子:
5.1
通讯作者:
C. Catalán;M. P. Lampasona;C. Cerda-García-Rojas;P. Joseph-Nathan
C. Catalán;M. P. Lampasona;C. Cerda-García-Rojas;P. Joseph-Nathan
中科院分区:
生物学2区
文献类型:
--
作者:
C. Catalán;M. P. Lampasona;C. Cerda-García-Rojas;P. Joseph-Nathan

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从枳实精油中分离到了3个新的倍半萜和S-(+)-反式神经梨醇。它们的结构经核磁共振鉴定为2β,4β,9α-2,6,6,9-四甲基三环[6.3.0,0,2,4]十一烷基-1(8)-烯-7,11-二酮[1],1β,2α,8β-2,6,10,10-四甲基双环[6.3]。O]十一-5-烯-2-醇(3 -羟基-6-星烯)[2]和1α,7β,9α-1-羟基-3,6,6,9-四甲基双环[5.4.0]十一-3-烯-8- 1[3]。
Three new sesquiterpenes, together with S-(+)-trans-nerolidol, were isolated from the essential oil of Lippia integrifolia. Their structures were elucidated by nmr spectroscopy as 2β,4β,9α-2,6,6,9-tetramethyltricyclo[6.3.0,0 2,4 ]undec-1(8)-ene-7,11-dione [1], 1β,2α,8β-2,6,10,10-tetramethylbicyclo[6.3.o]undec-5-en-2-ol (3a-hydroxy-6-asteriscene) [2], and 1α,7β,9α-1-hydroxy-3,6,6,9-tetramethylbicyclo[5.4.0]undec-3-en-8-one [3].