Facile synthesis of water-soluble LaF3 : Ln(3+) nanocrystals

Facile synthesis of water-soluble LaF3 : Ln(3+) nanocrystals
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DOI:
10.1039/b518262j
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发表时间:
2006-03
影响因子:
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通讯作者:
Feng Wang;Yong Zhang;X. Fan;Min-quan Wang
Feng Wang;Yong Zhang;X. Fan;Min-quan Wang
中科院分区:
--
文献类型:
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作者:
Feng Wang;Yong Zhang;X. Fan;Min-quan Wang

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采用简单的方法在低温水溶液中合成了水溶性镧系元素掺杂的LaF3纳米晶体。纳米晶体的形状接近球形,平均尺寸低于30 nm。它们由结晶良好的六方相组成。水溶液中的发光量子效率约为16%。合成了掺杂不同稀土离子(Eu3+、Ce3+、Tb3+ 和 Nd3+)的 LaF3 纳米晶体,在可见光(VIS)和近红外(NIR)光谱区表现出强发光。
Water-soluble lanthanide-doped LaF3 nanocrystals were synthesized using a simple method carried out in aqueous solution at low temperature. The nanocrystals have a nearly spherical shape and an average size of below 30 nm. They consisted of well crystallized hexagonal phases. The luminescence quantum efficiency was about 16% in aqueous solution. LaF3 nanocrystals doped with different lanthanide ions (Eu3+, Ce3+, Tb3+, and Nd3+) were synthesized, which showed strong luminescence in the visible (VIS) and near-infrared (NIR) spectral regions.