Dimethyl (1-hydr-oxy-1,2-diphenyl-ethyl)phospho-nate.

Dimethyl (1-hydr-oxy-1,2-diphenyl-ethyl)phospho-nate.
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(1-羟基-1,2-二苯基乙基)膦酸二甲酯。

DOI:
10.1107/s1600536809029808
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发表时间:
2009
期刊:
Acta crystallographica. Section E, Structure reports online
影响因子:
--
通讯作者:
Tariq,RiazH
Tariq,RiazH
中科院分区:
--
文献类型:
--
作者:
Tahir,MNawaz;Acar,Nurcan;Yilmaz,Hamza;Tariq,RiazH

文献摘要

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在标题化合物C16 H19 O 4P的晶体中,分子通过羟基和P=O O原子与R22(10)环基元二聚。芳环间的二面角为66.89(9)°。 相邻苄基的苯环之间存在π-π相互作用[质心-质心距离= 3.9669(16)π]。 芳香环之间也存在C-H π相互作用,其中C-H来自苄基。
In the crystal of the title compound, C16H19O4P, the molecules are dimerized with R22(10) ring motifs through the hydroxy and P=O O atoms. The dihedral angle between the aromatic rings is 66.89 (9)°. There are π–π interactions [centroid–centroid distance = 3.9669 (16) Å] between the benzene rings of adjacent benzyl groups. A C—H⋯π interaction between the aromatic rings where C—H is from a benzyl group is also present.