APPLICATION OF MICROWAVE DIELECTRIC LOSS HEATING EFFECTS FOR THE RAPID AND CONVENIENT SYNTHESIS OF RUTHENIUM(II) POLYPYRIDINE COMPLEXES
APPLICATION OF MICROWAVE DIELECTRIC LOSS HEATING EFFECTS FOR THE RAPID AND CONVENIENT SYNTHESIS OF RUTHENIUM(II) POLYPYRIDINE COMPLEXES
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DOI：
10.1007/bf01127876
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发表时间：
1991-02-01
影响因子：
1.7
通讯作者：
MINGOS, DMP
中科院分区：
文献类型：
--
作者：
GREENE, DL;MINGOS, DMP
The complexes [Ru(LL)3](PF6)2 [LL = 2,2'-bipyridine (bipy), 1, 10-phenanthroline (phen) and 4,4'-di-tertbutyl-2,2'-bipyridine (bipy*)] and [Ru(terpy)2](PF6)2 (terpy = 2,2',2"-terpyridine) have been rapidly and conveniently synthesised using microwave dielectric loss heating effects. The compounds were prepared in good yields (60-94%) in a Teflon autoclave, which can sustain temperatures up to 250-degrees-C and pressures of 80 atm, using MeOH as a solvent. Two 20s exposures to microwaves (2450 MHz and 650 W) were sufficient to achieve these yields.
