Thermal Expansion of 〈UN〉, 〈UO2〉, 〈UO2·ThO2〉, and 〈ThO2〉

Thermal Expansion of 〈UN〉, 〈UO2〉, 〈UO2·ThO2〉, and 〈ThO2〉
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〈UN〉、〈UO2〉、〈UO2·ThO2〉、〈ThO2〉的热膨胀

DOI:
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发表时间:
1959
期刊:
影响因子:
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通讯作者:
R. O. Elliott
R. O. Elliott
中科院分区:
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文献类型:
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作者:
C. P. Kempter;R. O. Elliott

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利用X射线衍射技术测定了多晶〈UN〉、〈UO2〉、〈UO2·ThO2〉固溶体和〈ThO2〉在室温到约1000°C之间的热膨胀特性。在26°至1000°C范围内,平均线性热膨胀系数(ᾱ×106/∘C)值分别为8.61、10.52、10.18和9.32。将观测到的<UO2·ThO2>晶格常数与E-an Zen方法计算出的晶格常数进行比较表明,随着温度的升高,固溶体变得不太理想。
The thermal expansion characteristics of polycrystalline 〈UN〉, 〈UO2〉, 〈UO2·ThO2〉 solid solution, and 〈ThO2〉 were determined between room temperature and ca 1000°C by means of x‐ray diffraction techniques. For the range 26° to 1000°C, the values of the average linear thermal expansion coefficients (ᾱ×106/∘C) are 8.61, 10.52, 10.18, and 9.32, respectively. A comparison of the observed 〈UO2·ThO2〉 lattice constants with those calculated by the method of E—an Zen indicates that the solid solution becomes less ideal as the temperature increases.