Electro-organic Syntheses for Green Chemical Manufacturing
Electro-organic Syntheses for Green Chemical Manufacturing
复制标题
用于绿色化学制造的有机电合成
DOI：
--
复制
发表时间：
2020
期刊：
影响因子：
--
通讯作者：
M. Modestino
中科院分区：
文献类型：
--
作者：
Elizabeth J. Biddinger;M. Modestino
虽然大规模电化学制造目前在氯碱生产或铝精炼等工艺中得到实践，但存在更广泛地实施电合成路线以实现有机化学品可持续生产的重大机会。本文讨论了化学制造中有机电合成的绿色化学优势。具体来说，我们讨论有机电合成路线如何实现化学制造的脱碳，使用电子作为产品和试剂如何减少废物的产生或危险试剂的使用，以及模块化反应器的实施如何实现非化石分布式化学原料的使用或按需生产化学品。最后，我们提供了关于大规模实施电合成过程的研发需求的观点。
While large-scale electrochemical manufacturing is currently practiced in processes such as chloro-alkali production or aluminum refining, significant opportunities exist to implement electrosynthesis routes more broadly for the sustainable production of organic chemicals. This article discusses green chemistry advantages of electro-organic syntheses for chemical manufacturing. Specifically, we discuss how organic electrosynthesis routes may enable the decarbonization of chemical manufacturing, how the use of electrons as products and reagents can reduce the generation of waste or the use hazardous reagents, and how the implementation of modular reactors may enable the use of non-fossil distributed chemical feedstocks or the production of chemicals on-demand. Lastly, we provide a perspective on the research and development needs to implement electrosynthesis processes at scale.