Regioselective nitration of 1-acyl-4-methoxyindolines leads to efficient synthesis of a photolabile L-glutamate precursor
Regioselective nitration of 1-acyl-4-methoxyindolines leads to efficient synthesis of a photolabile L-glutamate precursor
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DOI：
10.1081/scc-120004148
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发表时间：
2002-01-01
影响因子：
2.1
通讯作者：
Corrie, JET
中科院分区：
文献类型：
--
作者：
Papageorgiou, G;Corrie, JET
不同的硝化试剂产生不同比例的标题二氢吲哚的5-和7-硝基异构体。用粘土-乙酸酐获得了7-硝基异构体的最佳比例，这些条件对于制备光不稳定的L-谷氨酸衍生物特别有用。
Different nitrating reagents give different ratios of 5- and 7-nitro isomers of the title indolines. The best ratio of the 7-nitro isomer was obtained with claycop-acetic anhydride, and these conditions were particularly useful for preparation of a photolabile L-glutamate derivative.