New opportunities for materials synthesis using mechanochemistry
New opportunities for materials synthesis using mechanochemistry
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DOI：
10.1039/c0jm00872a
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发表时间：
2010-01-01
影响因子：
--
通讯作者：
Friscic, Tomislav
中科院分区：
文献类型：
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作者：
Friscic, Tomislav
机械化学合成在有机和金属有机材料领域正在经历一个动态的重新发现。新兴的机械化学方法，如液体辅助研磨（LAG）或离子和液体辅助研磨（ILAG），通过向固态反应中加入近化学计量的液相来实现增强的分子流动性，并通过催化和模板效应来辅助。本文重点介绍了这些温和的机械化学方法的令人兴奋的应用领域：“软”金属有机和有机材料的一锅组装，以及直接从金属氧化物快速室温合成多孔金属有机框架。
Mechanochemical synthesis is experiencing a dynamic re-discovery in the areas of organic and metal-organic materials. Emerging mechanochemical methods, such as liquid-assisted grinding (LAG) or ion-and liquid-assisted grinding (ILAG) achieve enhanced molecular mobility through the addition of near-stoichiometric amounts of a liquid phase to a solid-state reaction, and are aided by catalytic and templating effects. This article highlights the exciting areas of application for these mild mechanochemical methods: one-pot assembly of "soft'' metal-organic and organic materials, and the rapid room-temperature synthesis of porous metal-organic frameworks directly from a metal oxide.