Construction of a Highly Symmetric Nanosphere via a One-Pot Reaction of a Tristerpyridine Ligand with Ru(II)
Construction of a Highly Symmetric Nanosphere via a One-Pot Reaction of a Tristerpyridine Ligand with Ru(II)
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通过三三吡啶配体与 Ru(II) 的一锅反应构建高度对称的纳米球
DOI：
10.1021/ja502962j
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发表时间：
2014
影响因子：
15
通讯作者：
Newkome George R.
中科院分区：
文献类型：
--
作者：
Xie Ting-Zheng;Liao Sheng-Yun;Guo Kai;Lu Xiaocun;Dong Xuehui;Huang Mingjun;Moorefield Charles N.;Cheng Stephen Z. D.;Liu Xin;Wesdemiotis Chrys;Newkome George R.
通过四个新型三齿配体与六个钌离子的配位，合成了一个三维的、高度对称的三联吡啶类球形配合物，该配合物在较宽的pH值范围内（1-14）表现出优异的稳定性。通过NMR和ESI-TWIM-MS进行结构确认。
A three-dimensional, highly symmetric, terpyridine-based, spherical complex was synthesized via the coordination of four novel, trisdentate ligands and six Ru2+ions, and it exhibits excellent stability over a wide range of pH values (1–14). Structural confirmation was obtained by NMR and ESI-TWIM-MS.