Covalent Organic Frameworks-Organic Chemistry Beyond the Molecule
Covalent Organic Frameworks-Organic Chemistry Beyond the Molecule
复制标题
共价有机框架——超越分子层面的有机化学
DOI：
10.3390/molecules22091575
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发表时间：
2017-09-01
期刊：
影响因子：
4.6
通讯作者：
Yaghi, Omar M.
中科院分区：
文献类型：
--
作者：
Diercks, Christian S.;Kalmutzki, Markus J.;Yaghi, Omar M.
有机分子合成的核心是纯度、结构的确定性以及通过化学反应获得特定原子的能力。当考虑扩展的有机结构时，共价有机框架（COF）作为分子有机化学向固态的真正扩展而脱颖而出，因为分子有机化学的这三个基本属性被保留。COF是多孔的这一事实提供了有限的空间，在该空间内分子可以被进一步修饰和控制。
The synthesis of organic molecules has at its core, purity, definitiveness of structure, and the ability to access specific atoms through chemical reactions. When considering extended organic structures, covalent organic frameworks (COFs) stand out as a true extension of molecular organic chemistry to the solid state, because these three fundamental attributes of molecular organic chemistry are preserved. The fact that COFs are porous provides confined space within which molecules can be further modified and controlled.