Regioselective Hydroformylation of Sulfonamides using a Scaffolding Ligand
Regioselective Hydroformylation of Sulfonamides using a Scaffolding Ligand
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DOI：
10.1021/ol900921e
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发表时间：
2009-07-02
期刊：
影响因子：
5.2
通讯作者：
Tan, Kian L.
中科院分区：
文献类型：
--
作者：
Worthy, Amanda D.;Gagnon, Moriah M.;Tan, Kian L.
利用催化导向基团，发展了一种高区域选择性的烯丙基磺酰胺加氢反应。该反应容忍了广泛的电子和空间改性的烯烃，只有10%的骨架配体是需要有效地控制区域选择性。
A highly regioselective hydroformylation of allylic sulfonamides has been developed by employing a catalytic directing group. The reaction tolerates a wide range of electronically and sterically modified olefins, and only 10% of the scaffolding ligand is required to effectively control the regioselectivity.