Helix-sense-selective Polymerization of Achiral Acetylene Monomer Catalyzed by Rh Zwitterionic Complexes with Tethered Chiral Amino and Ether Groups
Helix-sense-selective Polymerization of Achiral Acetylene Monomer Catalyzed by Rh Zwitterionic Complexes with Tethered Chiral Amino and Ether Groups
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DOI：
10.1246/cl.2013.278
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发表时间：
2013-03
影响因子：
1.6
通讯作者：
Naoya Onishi;T. Aoki;T. Kaneko;M. Teraguchi;N. Sano;T. Masuda;M. Shiotsuki;F. Sanda
中科院分区：
文献类型：
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作者：
Naoya Onishi;T. Aoki;T. Kaneko;M. Teraguchi;N. Sano;T. Masuda;M. Shiotsuki;F. Sanda
通过[（C2 H4）2 RhCl]2与2，5-降冰片二烯反应，合成了带有手性氨基和醚基的两性离子铑配合物（CH 2）4 R [2：R =（R）-NHCH（CH 3）Ph.
Zwitterionic rhodium (Rh) complexes with tethered chiral amino and ether groups were synthesized by the reaction of [(C2H4)2RhCl]2 with the 2,5-norbornadiene tether, (CH2)4R [2: R = (R)-NHCH(CH3)Ph...