Highly efficient detection of ofloxacin in water by samarium oxide and β-cyclodextrin-modified laser-induced graphene electrode
Highly efficient detection of ofloxacin in water by samarium oxide and β-cyclodextrin-modified laser-induced graphene electrode
复制标题
氧化钐和β-环糊精修饰激光诱导石墨烯电极高效检测水中的氧氟沙星
DOI：
10.1016/j.microc.2022.108353
复制
发表时间：
2022-12-31
影响因子：
4.8
通讯作者：
Xie, Haijiao
中科院分区：
文献类型：
--
作者：
Liu, Zeyu;Wang, Qun;Xie, Haijiao
We developed a new electrochemical sensor that detects ofloxacin (OFL) in water by depositing beta-cyclodextrin (beta-CD) and samarium oxide nanoparticles (Sm2O3 NPs) onto a laser-induced graphene (LIG) electrode. Scanning electron microscopy, Transmission electron microscopy, Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, X-ray diffraction, contact angle measurements, and electrochemical impedance spectroscopy were used to characterize beta-CD/Sm2O3 NPs/LIG electrodes. Our results showed that the improved electrochemical activity is due to the excellent electrocatalytic performance of Sm2O3 NPs, improving electron transfer efficiency. The deposition of beta-CD improves electrode hydrophilicity and increases the adsorption capacity of OFL on the electrode surface. The synergistic effect of two modification compositions can promote OFL detection. The enhanced adsorption energy and improved electron transfer characteristics were also confirmed by density functional theory calculations. Under optimal detection conditions, the sensor achieves a wide linear range (0.01 similar to 1.0 mu mol/L and 1.0 similar to 120 mu mol/L) and a low detection limit (0.005 mu mol/L) with good anti-interference ability and stability. This sensor has also been successfully applied to the detection of OFL in tap water and lake water. These results show that the developed sensor is a promising step towards rapid in situ detection of OFL in water environments.
