Dye-sensitized CuAlO2 photocathodes for tandem solar cell applications

Dye-sensitized CuAlO2 photocathodes for tandem solar cell applications
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DOI:
10.1117/1.3528236
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发表时间:
2011
影响因子:
1.7
通讯作者:
A. Nattestad;X. Zhang;U. Bach;Yi-bing Cheng
A. Nattestad;X. Zhang;U. Bach;Yi-bing Cheng
中科院分区:
工程技术4区
文献类型:
--
作者:
A. Nattestad;X. Zhang;U. Bach;Yi-bing Cheng

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使用p型半导体CuAlO 2,结合高效空穴注入染料和碘化物-三碘化物基电解质制备了染料敏化太阳能电池(DSC),展示了光阴极行为。与使用NiO的类似器件相比,观察到333 mV的改进的开路电压(VOC),这可以通过CuAlO 2价带能量来解释,其在真空尺度上低于NiO的价带能量。入射光子-电荷载流子效率响应证实了所观察到的光电流是由染料产生的。2011年,由美国光电仪器工程师学会(SPIE)
Dye-sensitized solar cells (DSCs) using the p-type semiconductor CuAlO2, in con- junction with a highly effective hole injecting dye and an iodide-triiodide-based electrolyte have been produced, demonstrating photocathodic behavior. An improved open-circuit volt- age (VOC) of 333 mV was observed, compared to analogous devices using NiO, which can be explained by the CuAlO2 valence-band energy, which is lower on the vacuum scale than that of NiO. Incident photon-to-charge-carrier efficiency response confirms that the observed photocurrent is generated by the dye. C 2011 Society of Photo-Optical Instrumentation Engineers (SPIE).