A Ratiometric Fluorescent Probe for Hypochlorite Based on a Deoximation Reaction
A Ratiometric Fluorescent Probe for Hypochlorite Based on a Deoximation Reaction
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基于脱肟反应的次氯酸盐比率荧光探针
DOI：
10.1002/chem.200802054
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发表时间：
2009-01-01
影响因子：
4.3
通讯作者：
Tan, Wen
中科院分区：
文献类型：
--
作者：
Lin, Weiying;Long, Lingliang;Tan, Wen
在这项工作中，我们成功地为合理设计和合成次氯酸盐比率荧光探针提供了一种新的策略，该策略基于脱氧反应，目前还没有用于次氯酸盐荧光探针的设计。有趣的是，该探针对次氯酸盐表现出比率荧光响应，发射强度比从0.28增加到2.74。此外，由于不同的脱肟条件，该探针对次氯酸盐表现出比其他物种更高的选择性。本文开发的探针是第一个用于次氯酸盐的比率荧光探针。
In this work, we have successfully provided a novel strategy for the rational design and synthesis of a ratiometric fluorescent probe for hypochlorite, The strategy is based on the deoximation reaction, which has not yet been used in the fluorescent hypochlorite probe design. Interestingly, the probe showed a ratiometric fluorescent response to hypochlorite with the emission intensities ratio increasing from 0.28 to 2.74. Furthermore, the probe displayed high selectivity for hypochlorite over other species due to the distinct deoximation conditions. The probe developed herein represents the first ratiometric fluorescent probe for hypochlorite.