Novel metal-free bis-silylation:: C60-sensitized reaction of disilirane with benzonitrile
Novel metal-free bis-silylation:: C60-sensitized reaction of disilirane with benzonitrile
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DOI：
10.1021/ol9901772
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发表时间：
1999-11-18
期刊：
影响因子：
5.2
通讯作者：
Horn, E
中科院分区：
文献类型：
--
作者：
Akasaka, T;Maeda, Y;Horn, E
[图表]二硅烷与C-60在苯甲腈中的光化学反应提供了二硅烷和苯甲腈的加合物作为双甲硅烷基化产物。在该反应中，C-60充当敏化剂。通过一种新颖的不饱和化合物的无金属双甲硅烷基化反应，通过光诱导电子转移过程的结果合理地占。
[GRAPHICS]The photochemical reaction of disilirane with C-60 in benzonitrile affords the adduct of disilirane and benzonitrile as a bis-silylated product. In this reaction, C-60 serves as a sensitizer. The results are reasonably accounted for by a novel metal-free bis-silylation of an unsaturated compound via a photoinduced electron-transfer process.