Chain Compounds Formed by the Reaction of Copper(II) Carboxylate [Cu2(O2CR)4] (R = C(CH3)3, CCl3) and Bridging Ligand L (L = Pyrazine, 4,4′-Bipyridine, and 1,4-Diazabicyclo[2.2.2]octane)
Chain Compounds Formed by the Reaction of Copper(II) Carboxylate [Cu2(O2CR)4] (R = C(CH3)3, CCl3) and Bridging Ligand L (L = Pyrazine, 4,4′-Bipyridine, and 1,4-Diazabicyclo[2.2.2]octane)
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羧酸铜(II) [Cu2(O2CR)4] (R = C(CH3)3, CCl3) 和桥连配体 L (L = 吡嗪、4,4′-联吡啶和 1,4) 反应形成的链状化合物-二氮杂双环[2.2.2]辛烷）
DOI：
10.1246/cl.1995.617
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发表时间：
1995
影响因子：
1.6
通讯作者：
M. Handa
中科院分区：
文献类型：
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作者：
M. Mikuriya;Ryoji Nukada;Hiroaki Morishita;M. Handa
羧酸铜(II) Cu2(O2CR)4 (R = C(CH3)3 和 CCl3) 与桥连配体 L (L = 吡嗪 (pyz)、4,4'-联吡啶 (4,4'-bpy) 和 1,4-二氮杂双环[2.2.2]辛烷 (dabco)) 反应得到化合物， [Cu2(O2CC(CH3)3)4L]n (L = pyz (1)、4,4'-bpy (2) 和 dabco (3))、[Cu2(O2CCCl3)4L2]·nH2O (L = pyz；n = 1 (4)，L = 4,4'-bpy；n = 1 (5)，L = dabco；n = 3 (6))，和[Cu4(OCH3)4(O2CCCl3)4(CH3OH)2(pyz)]n·2nCH3OH (7)。 1和7的X射线结构分析显示了其中羧酸酯二聚体单元或立方烷四核单元通过吡嗪分子连接的链结构。
Reaction of copper(II) carboxylates, Cu2(O2CR)4 (R = C(CH3)3 and CCl3) with bridging ligands, L (L = pyrazine (pyz), 4,4′-bipyridine (4,4′-bpy), and 1,4-diazabicyclo[2.2.2]octane (dabco)) gave compounds, [Cu2(O2CC(CH3)3)4L]n (L = pyz (1), 4,4′-bpy (2), and dabco (3)), [Cu2(O2CCCl3)4L2]·nH2O (L = pyz; n = 1 (4), L = 4,4′-bpy; n = 1 (5), and L = dabco; n = 3 (6)), and [Cu4(OCH3)4(O2CCCl3)4(CH3OH)2(pyz)]n·2nCH3OH (7). The X-ray structure analyses of 1 and 7 show chain structures where the carboxylate dimer units or the cubane tetranuclear units are linked by the pyrazine molecules.